Sodium cyanide, as used in the m44 device, is considered to be a high acute risk pesticide for terrestrial vertebrates, including nontarget and endangered birds and mammals. May cause eye and skin irritation with possible burns. Show this safety data sheet to the doctor in attendance. Chemical product and company identification product name. Hydrogen cyanide gas released by sodium cyanide has a distinctive mild, bitter almond odor, but a large proportion of people cannot detect it. Vacuum or sweep up material and place into a suitable disposal container. The structure of solid nacn is related to that of sodium chloride, in which the numbers of cations and anions are equal with six coordinates. Sodium cyanide sodium cyanide has been used in the extraction of gold from ore for over a century. The sodium carbonate that forms in the absorption is not removed prior to crystallization. Supplemental hazard information eu euh031 contact with acids liberates toxic gas. Cdc niosh pocket guide to chemical hazards sodium cyanide. Sodium cyanide cas 143339 emplura find msds or sds, a coa, data sheets and more information. Msds contains all of the information required by those regulations. Jan 25, 2017 solution sodium cyanide msds english jan 25, 2017, 12.
Alkaline cyanide reagent solution catalogue number. This material contains copper i cyanide listed as copper compounds, n. Commercial production of sodium cyanide is achieved by reacting sodium carbonate with carbon and ammonia. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Sodium cyanide formula, structure, msds, uses and properties. Environmental protection and toxic substances september 1994 agency h7508w r. Environmental protection and toxic substances september.
Sodium cyanide is a restricted use pesticide from which endangered species may not currently be adequately protected. Cyanide has a high affinity for metals, which leads to the high toxicity of this salt. Sodium cyanide 30% solution other names sodium cyanide solution, liquid cyanide. Safety data sheet revision date 19jan2018 revision number 3 1. Summary of subchronic and chronic oral toxicity studies for cyanide in animals 56 47. Identification of the substancemixture and of the companyundertaking 1. Cyanides of hydrogen, sodium and potassium, and acetone cyanohydrin cas no. Sodium cyanide in contact with acids or weak alkalies liberates highly toxic and flammable hydrocyanic acid hcn gas.
May be metabolized to cyanide which, in turn, acts by inhibiting cytochrome oxidase impairing cellular respiration. Use suitable protective equipment see section 8 exposure controlspersonal protection. Sodium dithionite cas no 7775146 material safety data sheet sdsmsds. Page 4 of 7 msds t acetonitrile personal protection in case of a large spill. This material does not contain any class 1 ozone depletors. To ensure the safety of our customers, orica offers a 247 emergency response capability, plus technical advice and awareness programs in the safe use and handling of cyanide on mine sites. Incompatible with strong oxidizing agents, especially if solution dries out. Summary of subchronic and chronic inhalation toxicity studies for cyanide in humans 59 51. Cyanides of hydrogen, sodium and potassium, and acetone. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or selfcontained breathing apparatus. Each sodium ion forms pibonds with two cn groups, two bent nacn, and two bent. Safety data sheet sodium cyanide solution pages 1 12 text.
It absorbs water from air is hygroscopic or deliquescent. Label elements ghs label elements the product is classified and labelled according to the globally harmonized system ghs. When treated with acid, it forms the toxic gas hydrogen cyanide. Gives insoluble products with silveri, mercuryi and leadii ions that may decompose violently under certain conditions. Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone. Sodium nitrite 300600 mg administered intravenously over a period of 5 to 15 minutes. First aid facilities first aid procedures, equipment, medication and training for the treatment of exposure. Material safety data sheet sodium thiocyanate, acs 3 spillsleaks. Solution sodium cyanide msds english jan 25, 2017, 12. Clean up spills immediately, observing precautions in the protective equipment section. Sodium dithionite material safety data sheet cas no.
The recommended cyanide antidote kit to be kept by user for use. The material safety data sheet is for this gas mixture supplied in cylinders. Us4847062a process for production of sodium cyanide. Sodium cyanide is used as a starting material for the preparation of reissert compounds and cyanogen bromide, cyanuric chloride and cyanogen chloride. Uses advised against food, drug, pesticide or biocidal product use. No action shall be taken involving any personal risk or without suitable training. California, new jersey, florida, pennsylvania, minnesota, massachusetts.
Sodium cyanide, reagent grade, 97% nacn sigmaaldrich. Sodium hydroxide can be found on the following state righttoknow lists. Its main application, in gold mining, also exploits its high reactivity toward metals. Controlled products regulations and the msds contains all the information required by the controlled products regulations. If patient is conscious, then sodium thiosulfate may be administered as an antidote by itself. Inventing and reinventing sodium cyanide ejectors a technical history of coyote getters and m44s in predator damage control f. Identification of the substancemixture and of the companyundertakingtrade name sodium cyanide solutionsynonyms sodium cyanide solutionun number 3414emergency response 157guide erg sasol polymerscompany chlor vinyls business 56 grosvenor road bryanston 2021 republic of south africainformation product safety. Today it is still considered the most efficient extraction method with sodium cyanide used in the leaching process in most gold mining operations. Sheet sds should be referred to as it contains relevant information on the chemicals hazards. Liquid sodium cyanide is delivered to mine sites via purposebuilt isotanks that are suitable for road or rail transport. Avoid runoff into storm sewers and ditches that lead to waterways. None of the chemicals in this product are considered highly hazardous by osha. Material safety data sheet pharmaceutical chemistry.
It can be used to extract metals from ores and also has been used as a poison. It acts as a catalyst for the aminolysis of esters to primary amides. Sodium cyanide is shipped as pellets or briquettes. Also toxic amounts of hcn can be liberated from water solutions of sodium cyanide. Australian gold reagents is a manufacturer and supplier of sodium cyanide for the mining industry. Harmful if swallowed, inhaled, or absorbed through the skin. It includes guidance on recognising symptoms of cyanide poisoning. Acids should not be used around sodium cyanide or potassium cyanide unless absolutely necessary and then only after careful planning. Material safety data sheet sodium nitroprusside, acs. Sodium cyanide safety data sheet according to regulation ec no 19072006 reach, annex ii commission regulation eu no 2015830 5 7. Safety data sheet northwest missouri state university.
A process for producing anhydrous sodium cyanide crystals by absorbing hydrogen cyanide synthesis gas that contains oxides of carbon and water in aqueous sodium hydroxide and crystallizing the sodium cyanide solution that results from the absorption. Ac180562500 synonyms sodium isocyanate recommended use laboratory chemicals. Sodium hydroxide safety data sheet according to federal register vol. Facts sodium cyanide pesticide reregistration all pesticides sold or distributed in the united states must be registered by epa, based on scientific studies showing that they can be used without posing unreasonable risks to people or the environment. This material does not contain any hazardous air pollutants. Cyanide standard, ppm safety data sheet according to federal register vol. Material safety data sheet cyanide standard, ppm 6 osha highly hazardous. Safety data sheet production, delivery and usage of sodium. L530620 application of the substance the preparation reagent for water analysis. Reacts with acids of all kinds to generate quantities of very poisonous hydrogen cyanide gas. Reproductive endpoints in male rats and mice observed following administration of. Department of agriculture, animal plant and health inspection service, wildlife services, pocatello, idaho 83201.
Sodium nitroprusside dihydrate releases nitric oxide in vivo, induces vasodilation, and inhibits platelet. For manufacturing, industrial, and laboratory use only. Material safety data sheet sodium nitroprusside, acs 2 inhalation. Hydrogen cyanide hcn formation is the greatest potential hazard in using sodium cyanide or potassium cyanide solutions because some hcn gas will be released. Material safety data sheet sodium cyanide section 1 chemical product and company identification msds name. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Two ampoules of sterile sodium nitrite solution 10 ml of a 3%. Furthermore, it is used for fumigation, electroplating, extracting gold. Nitrogen trichloride explodes on contact with potassium cyanide. Safety data sheet according to federal register vol. Section 3 no chemicals are reportable under section 3. Sodium cyanide solution is not combustible and is not considered a fire risk, but may generate toxic, flammable, corrosive and explosive hydrogen cyanide gas if in contact with water, co 2 fire extinguishers, and some foam fire extinguishers if these contain acidic agents. Canadian ingredient disclosure list section 16 additional information msds creation date. Sodium cyanide safety data sheet according to commission regulation eu no no.
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